86310-01-2

Basic information

• Product Name: 3-Penten-2-one, 4-(methylthio)-, (3E)- (9CI)
• Synonyms: 3-Penten-2-one, 4-(methylthio)-, (3E)- (9CI)
• CAS NO: 86310-01-2
• Molecular Formula: C₆H₁₀OS
• Molecular Weight: 130.208
• Product Categories: ACETYLGROUP
• Mol File: 86310-01-2.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3-Penten-2-one, 4-(methylthio)-, (3E)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Penten-2-one, 4-(methylthio)-, (3E)- (9CI)(86310-01-2)
• EPA Substance Registry System: 3-Penten-2-one, 4-(methylthio)-, (3E)- (9CI)(86310-01-2)

Safety Data

• Hazardous Substances Data: 86310-01-2(Hazardous Substances Data)

Upstream product

• 624-92-0 Dimethyldisulphide 
• 560095-47-8 (3-buten-2-yl)pentamethyl phosphoric triamide 
• 17649-86-4 4,4-bis(methylthio)but-3-en-2-one 
• 917-54-4 methyllithium 

Downstream Products

• 675-09-2 4,6-Dimethyl-2-pyron 

Relevant articles and documents

New ketone homoenolate anion equivalents derived from (alkenyl)pentamethyl phosphoric triamides

Lithiated ambident anions derived from (1-alkyl-2-propenyl)- or (1-phenyl-2-propenyl)-pentamethyl phosphoric triamides undergo regioselectively γ-reaction with various alkylating reagents and isobutyraldehyde. Further hydrolysis of adducts releases the ketone under acid conditions. Number of synthetic applications clearly show the ketone homoenolate behaviour of these new carbanions.