86311-86-6Relevant academic research and scientific papers
Convenient Preparation of Dimethyl (Trifluoromethyl)malonate and Related Compounds
Ishikawa, Nobuo,Yokozawa, Tsutomu
, p. 724 - 726 (2007/10/02)
The preparative method for dimethyl (trifluoromethyl)malonate (4) from the adduct of perfluoro-2-methylpropene with methanol was improved, and several reactions of this base-sensitive substance were investigated.Alkylation of 4 was achieved by using CsF as a condensing agent, and the Michael addition on vinyl ketones proceeded in triethylamine-pyridine medium.
