863582-36-9

Upstream product

• 37051-70-0 4-methyl-N-(4-oxocyclohexa-2,5-dien-1-ylidene)benzenesulfonamide 
• 1146-43-6 N-(4-hydroxyphenyl)-4-methylbenzenesulfonamide 
• 863582-11-0 N-(4-hydroxy-8-methyl-5,8-dihydro-naphthalen-1-yl)-4-methyl-benzenesulfonamide 
• 863582-27-8 trifluoro-methanesulfonic acid 5-methyl-4-(toluene-4-sulfonylamino)-5,8-dihydro-naphthalen-1-yl ester 

Downstream Products

• 891718-67-5 [3-methyl-1-(toluene-4-sulfonyl)-5-vinyl-1H-indol-4-yl]-acetaldehyde 
• 891719-07-6 3-methyl-4-(4-oxo-pent-2-enyl)-1-(toluene-4-sulfonyl)-1H-indole-5-carbaldehyde 
• 891718-59-5 acetic acid 2-[3-methyl-1-(toluene-4-sulfonyl)-5-vinyl-1H-indol-4-yl]-ethyl ester 
• 891718-99-3 5-[3-methyl-1-(toluene-4-sulfonyl)-5-vinyl-1H-indol-4-yl]-pent-3-en-2-one 
• 891718-83-5 4-[5-formyl-3-methyl-1-(toluene-4-sulfonyl)-1H-indol-4-yl]-but-2-enoic acid methyl ester 
• 891718-75-5 4-[3-methyl-1-(toluene-4-sulfonyl)-5-vinyl-1H-indol-4-yl]-but-2-enoic acid methyl ester 
• 891718-51-7 acetic acid 2-[3-methyl-1-(toluene-4-sulfonyl)-5-trifluoromethanesulfonyloxy-1H-indol-4-yl]-ethyl ester 
• 869468-99-5 trifluoro-methanesulfonic acid 4-(2-methoxycarbonyloxy-ethyl)-3-methyl-1-(toluene-4-sulfonyl)-1H-indol-5-yl ester 

Relevant academic research and scientific papers

Synthesis of the western half of the lolicines and lolitrems

The synthesis of the highly substituted indole portion of the complex tremorgenic natural products lolicine A and B is presented. The Diels-Alder reaction of a quinone monoimine enables the synthesis of an appropriately substituted indole. The key step in

Synthesis and cross-coupling reactions of substituted 5-triflyloxyindoles

N-Arylsulfonyl quinone monoimines undergo smooth cycloadditions in a [4+2] sense to yield the expected cycloadducts. The crude cycloadducts, when subjected to a short series of simple transformations, produce synthetically useful quantities of 5-triflylox