86377-32-4Relevant academic research and scientific papers
STABLE CARBOCATIONS FROM TERPENOIDS. VIII. MOLECULAR REARRANGEMENTS OF CARYOPHYLLENE AND CLOVENE IN SUPERACIDS
Gatilova, V. P.,Korchagina, D. V.,Rybalova, T. V.,Batilov, Yu. V.,Dubovenko, Zh. V.,Barkhash, V. A.
, p. 285 - 295 (2007/10/02)
The conformational composition of caryophyllene was analyzed by the computational methods of molecular mechanics and also the 13C NMR spectra.The conformationally controlled reactions of caryophyllene in superacids lead to mixtures of tricyclic compounds with new types of skeletons, which can be produced as the sum of the products from the "quenching" of the ions formed from clovene and 1-substituted caryolanes under the same conditions.
STABLE CARBOCATIONS FROM TERPENOIDS. V. REARRANGEMENTS OF 1-SUBSTITUTED CARYOLANES IN SUPERACIDS
Gatilova, V. P.,Korchagina, D. V.,Bagryanskaya, I. Yu.,Gatilov, Yu. V.,Dubovenko, Zh. V.,et al.
, p. 5 - 19 (2007/10/02)
An experimentally substantiated scheme is proposed for the molecular rearrangements of 1-substituted caryolanes in acidic media.The behavior pattern of the intermediately formed polycyclic carbocations observed under "long-life" conditions agrees with the rearrangement paths predicted on the basis of analysis within the scope of molecular mechanics.
