863870-72-8Relevant articles and documents
Development of an enolate alkynylation approach towards the synthesis of the taiwanschirin natural products
Christensen, Kirsten E.,Donohoe, Timothy J.,Haughey, Maxwell B.,Poole, Darren L.
, p. 13392 - 13397 (2021/11/01)
Through the use of model studies, an approach was conceived towards the synthesis of the taiwanschirin family of natural products. These are structurally complex compounds which represent highly challenging and biologically active targets for total synthesis. This work describes a successful synthesis of the complex taiwanschirin fused [8,6,5] core through a novel alkynylation reaction coupled with an intramolecular Heck reaction used to construct the 8-membered ring.
Palladium-Catalyzed Regioselective Synthesis of 1-Hydroxycarbazoles Under Aerobic Conditions
Youn, So Won,Kim, Young Ho,Jo, Yoon Hyung
supporting information, p. 462 - 468 (2019/01/04)
A palladium-catalyzed aerobic C?H amidation of N-Ts-2-amino-3′-hydroxylbiaryls has been developed to afford a diverse range of 1-hydroxycarbazoles with high regioselectivity and efficiency. This protocol benefits from operational simplicity, robustness, a
An Efficient and Modular Route to C 3?-TunePhos-Type Ligands
Deng, Xu,Guan, Yu-Qing,Huo, Ning-Ning,Wang, Ya-Jing,Lv, Hui,Zhang, Xu-Mu
supporting information, p. 3726 - 3730 (2017/08/16)
An efficient and modular synthetic route to the bidentate C 3?-TunePhos was developed, which allowed tunable steric and electronic effects of the ligands. This novel chemical technology highlights a versatile C 3?-dibromodiphenyl int
