86396-12-5

Basic information

• Product Name: Iodonium, phenyl-, 6-methyl-2,4-dioxo-2H-pyran-3(4H)-ylide
• CAS NO: 86396-12-5
• Molecular Formula: C12H9IO3
• Molecular Weight: 328.106
• Mol File: 86396-12-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Iodonium, phenyl-, 6-methyl-2,4-dioxo-2H-pyran-3(4H)-ylide(CAS DataBase Reference)
• NIST Chemistry Reference: Iodonium, phenyl-, 6-methyl-2,4-dioxo-2H-pyran-3(4H)-ylide(86396-12-5)
• EPA Substance Registry System: Iodonium, phenyl-, 6-methyl-2,4-dioxo-2H-pyran-3(4H)-ylide(86396-12-5)

Safety Data

• Hazardous Substances Data: 86396-12-5(Hazardous Substances Data)

Upstream product

• 675-10-5 4-hydroxy-6-methyl-2-pyron 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Relevant articles and documents

Ylides of Heterocycles, V. I-, N- and S-Ylides of 2-Pyrones and 2-Pyridones

The reaction of the pyrone 1a or the pyridones 1b,c with iodosobenzene leads to the iodonium-ylides 2 which undergo thermal rearrangement to the 4-phenyloxy-3-iodo compounds 3.Reductive deiodination of 3 gives the 4-phenyloxy compounds 4.By acid catalyzed