863971-66-8 Usage
Reaction
Ligand/Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
Ligand/ catalyst for the hydrogenation of esters in high yields under mild pressure and neutral conditions.
Ligand/Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields under neutral conditions.
Ligand/Catalytic hydrogenation of dimethyl carbonate, methyl carbamates, and methyl formate, a route to methanol based on CO and CO2.
Check Digit Verification of cas no
The CAS Registry Mumber 863971-66-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 8,6,3,9,7 and 1 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 863971-66:
(8*8)+(7*6)+(6*3)+(5*9)+(4*7)+(3*1)+(2*6)+(1*6)=218
218 % 10 = 8
So 863971-66-8 is a valid CAS Registry Number.
863971-66-8Relevant articles and documents
Facile conversion of alcohols into esters and dihydrogen catalyzed by new ruthenium complexes
Zhang, Jing,Leitus, Gregory,Ben-David, Yehoshoa,Milstein, David
, p. 10840 - 10841 (2005)
An efficient, environmentally benign method for the preparation of esters from alcohols under mild, neutral conditions without the need for carboxylic acid derivatives and condensing agents was developed. Catalyst design, based on new Ru(II) hydrido carbonyl complexes incorporating electron-rich PNP and PNN ligands has resulted in the novel complex (I) which is an outstanding catalyst for the dehydrogenation of primary alcohols to esters and H2 under neutral conditions. Copyright
