863973-73-3Relevant academic research and scientific papers
Metal-free catalytic hydrogenation
Chase, Preston A.,Welch, Gregory C.,Jurca, Titel,Stephan, Douglas W.
, p. 8050 - 8053 (2007)
(Chemical Equation Presented) Phosphonium borates of the form R 2PH-(C6F4)BH(C6F5) 2 are shown to be metalfree hydrogenation catalysts (see scheme) that effect reduction of sterically hindered imines and aziridines, as well as B(C6F5)3-protected unhindered imines and nitriles, at relatively low H2 pressures and temperatures.
Intra- and intermolecular N-H...F-C hydrogen-bonding interactions in amine adducts of tris(pentafluorophenyl)borane and -alane
Mountford, Andrew J.,Lancaster, Simon J.,Coles, Simon J.,Horton, Peter N.,Hughes, David L.,Hursthouse, Michael B.,Light, Mark E.
, p. 5921 - 5933 (2008/10/09)
The reaction between B(C6F5)3 and NH 3(g) in light petroleum yielded the solvated adduct H 3N·B(C6F5)3·NH 3. Treatment with a second equivalent of B(C6
