86401-99-2Relevant articles and documents
Convenient fabrication of carbon doped WO3?x ultrathin nanosheets for photocatalytic aerobic oxidation of amines
Bao, Keyan,Zhang, Shaojie,Ni, Ping,Zhang, Zixiang,Zhang, Kailong,Wang, Liangbiao,Sun, Li Xia,Mao, Wutao,Zhou, Quanfa,Qian, Yitai
, p. 311 - 317 (2018/11/23)
It is an important chemical transformation for oxidation of amines to imines, on account of very important versatile applications of imines in organic synthesis. Here, we develop a convenient way to synthesize carbon doped WO3?x ultrathin nanos
Diastereodivergent [3 + 2] Annulation of Aromatic Aldimines with Alkenes via C-H Activation by Half-Sandwich Rare-Earth Catalysts
Cong, Xuefeng,Hou, Zhaomin,Mo, Zhenbo,Nishiura, Masayoshi,Zhan, Gu
supporting information, p. 5531 - 5537 (2020/04/09)
Stereodivergent catalysis is of great importance, as it can allow efficient access to all possible stereoisomers of a given product with multiple stereocenters from the same set of starting materials. We report herein the first diastereodivergent [3 + 2]
A Metal-Free Approach to 1,2-Diamines via Visible Light-Driven Reductive Coupling of Imines with Perylene as a Photoredox Catalyst
Okamoto, Shusuke,Ariki, Risako,Tsujioka, Hiroki,Sudo, Atsushi
, p. 9731 - 9736 (2017/09/23)
A simple, metal-free, and versatile approach to 1,2-diamines has been developed based on reductive coupling reactions of various imines, where perylene, an aromatic hydrocarbon, was used as a photoredox catalyst under visible light irradiation using a white light-emitting diode. The use of 1 mol % perylene enabled almost complete conversion of the imines, leading to the formation of their corresponding 1,2-diamines, which were isolated in good yields. The ratios between dl and meso diamines ranged from 31:69 to 82:18 depending on the substituents of the imines.
