864067-05-0

Basic information

• Product Name: 5-bromo-2-[2-(4-bromo-phenoxy)-ethoxy]-pyridine
• Synonyms: 5-bromo-2-[2-(4-bromo-phenoxy)-ethoxy]-pyridine
• CAS NO: 864067-05-0
• Molecular Formula: C₁₃H₁₁Br₂NO₂
• Molecular Weight: 373
• Mol File: 864067-05-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-bromo-2-[2-(4-bromo-phenoxy)-ethoxy]-pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 5-bromo-2-[2-(4-bromo-phenoxy)-ethoxy]-pyridine(864067-05-0)
• EPA Substance Registry System: 5-bromo-2-[2-(4-bromo-phenoxy)-ethoxy]-pyridine(864067-05-0)

Safety Data

• Hazardous Substances Data: 864067-05-0(Hazardous Substances Data)

Upstream product

• 624-28-2 2,5-dibromopyridine 
• 34743-88-9 2-(4-bromophenoxy)ethanol 
• 106-41-2 4-bromo-phenol 

Downstream Products

• 7659-55-4 5-ethenyl-2-[2-(4-ethenylphenoxy)ethoxy]pyridine 

Relevant articles and documents

The exo-outstretching effect governing the exclusive stereoselectivity of the intramolecular [2 + 2] photocycloaddition of vinylarenes

Intramolecular [2 + 2] photocycloaddition of a dimeric vinylpyridine 1 through a singlet-excited species efficiently formed the corresponding syn- and anti-pyridinophanes 2 and 3. The syn-isomers were elucidated spectroscopically and by X-ray crystallography as exo,syn-configured. The high selectivity under formation of exo,syn-2 was thoroughly investigated. Consequently, an exo-outstretching effect, which is observed around the periphery of a face-to-face-oriented system between two aromatic nuclei as a transition state, on cyclobutane ring formation was discovered for the first time.