86410-99-3Relevant academic research and scientific papers
Palladium-catalyzed heck-type reactions of alkyl iodides
Bloome, Kayla S.,McMahen, Rebecca L.,Alexanian, Erik J.
, p. 20146 - 20148 (2012/02/01)
A palladium-catalyzed Heck-type reaction of unactivated alkyl iodides is described. This process displays broad substrate scope with respect to both alkene and alkyl iodide components and provides efficient access to a variety of cyclic products. The reaction is proposed to proceed via a hybrid organometallic-radical mechanism, facilitating the Heck-type process with alkyl halide coupling partners. Initial intermolecular studies are also reported, demonstrating the potentially wide applicability of this approach in synthesis.
Ene Reaction Mechanisms. 2. Regioselectivity with N-Aryl-N'-p-tosylsulfur Diimides as Enophiles. Crystal Structure of N-(Pentafluorophenyl)-N'-p-tosylsulfur Diimide
Muensterer, Heribert,Kresze, Guenter,Lamm, Viktor,Gieren, Alfred
, p. 2833 - 2837 (2007/10/02)
The ene reactions of sulfur diimides TosNSNAr (1;Ar = C6H5, 4-O2NC6H4, and C6F5) with 2-methyl-2-butene (2) have been investigated.The products undergo a sigmatropic rearrangement.The structures of these rearranged products have been determined.Taki
