864150-33-4Relevant academic research and scientific papers
Synthesis and spectroscopic characterization of enantiopure protected trans-4-amino-1-oxyl-2,2,6,6-tetramethyl piperidine-3-carboxylic acid (trans β-TOAC)
Wright, Karen,Castries, Augustin De,Sarciaux, Matthieu,Formaggio, Fernando,Toniolo, Claudio,Toffoletti, Antonio,Wakselman, Michel,Mazaleyrat, Jean-Paul
, p. 5573 - 5576 (2005)
Enantiomerically pure (3R,4S) and (3S,4R) protected 4-amino-1-oxyl-2,2,6,6- tetramethylpiperidine-3-carboxylic acids were synthesized by reduction of the enamines resulting from the condensation of 3-carboxymethyl-1-oxyl-2,2,6,6- tetramethyl-4-piperidone
Synthesis of enantiomerically pure cis- and trans-4-amino-1-oxyl-2,2,6,6- tetramethylpiperidine-3-carboxylic acid: A spin-labelled, cyclic, chiral β-amino acid, and 3D-structural analysis of a doubly spin-labelled β-hexapeptide
Wright, Karen,Sarciaux, Matthieu,De Castries, Augustin,Wakselman, Michel,Mazaleyrat, Jean-Paul,Toffoletti, Antonio,Corvaja, Carlo,Crisma, Marco,Peggion, Cristina,Formaggio, Fernando,Toniolo, Claudio
, p. 3133 - 3144 (2008/02/09)
Animation of 3-carboxymethyl-1-oxyl-2,2,6,6-tetramethyl-4-piperidone (1) with either (R)- or (S)-α-methylbenzylamine gave corresponding enamines 2. Whereas the reduction with NaBH3CN/CH3COOH afforded predominantly a mixture of two po
