864152-68-1

Basic information

• Product Name: 2-(2-(allyloxy)phenyl)-4,4-dimethyl-4,5-dihydrooxazole
• Synonyms: 2-(2-(allyloxy)phenyl)-4,4-dimethyl-4,5-dihydrooxazole
• CAS NO: 864152-68-1
• Molecular Weight: 231.294
• Mol File: 864152-68-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(2-(allyloxy)phenyl)-4,4-dimethyl-4,5-dihydrooxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-(allyloxy)phenyl)-4,4-dimethyl-4,5-dihydrooxazole(864152-68-1)
• EPA Substance Registry System: 2-(2-(allyloxy)phenyl)-4,4-dimethyl-4,5-dihydrooxazole(864152-68-1)

Safety Data

• Hazardous Substances Data: 864152-68-1(Hazardous Substances Data)

Upstream product

• 52542-42-4 2-allyloxybenzoyl chloride 
• 611-20-1 salicylonitrile 
• 106-95-6 allyl bromide 
• 163165-91-1 2-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)-phenol 

Downstream Products

• 864152-69-2 2-(2'-hydroxy-3'-allylphenyl)-4,4-dimethyl-2-oxazoline 
• 163165-91-1 2-(4,4-dimethyl-4,5-dihydro-1,3-oxazol-2-yl)-phenol 

Relevant articles and documents

Base-Induced Cyclisation of ortho -Substituted 2-Phenyloxazolines to Give 3-Aminobenzofurans and Related Heterocycles

Treatment of ortho -benzyloxyphenyloxazolines with butyllithium and potassium tert -butoxide results in cyclisation with ring opening of the oxazoline to give 2-aryl-3-aminobenzofurans. The reaction also occurs with the corresponding benzylthio and benzylamino compounds to give benzothiophenes and indoles, respectively. Use of an ortho -allyloxyphenyloxazoline gives the corresponding 2-vinylbenzofuran, while both α-methylbenzyloxy and benzylsulfonyl compounds form stable spirooxazolidine products. The X-ray structure of an aminobenzothiophene product has been determined.