864155-67-9

Upstream product

• 864155-70-4 (Z)-(1R,4S,4aR,8S,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-1-hydroxy-8-methyl-1,4,4a,5,8,9,12,12a-octahydro-7-oxa-benzocyclodecen-6-one 
• 864155-61-3 [(1R,5R,6R)-6-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-oxo-cyclohex-3-enyl]-acetic acid ethyl ester 
• 864155-63-5 [(1R,2S,5R,6R)-6-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-hydroxy-cyclohex-3-enyl]-acetic acid ethyl ester 
• 146830-47-9 (1S,4R,4aS,5R,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-ol 
• 146830-46-8 Acetic acid (1S,4R,4aS,5R,8S,8aR)-8-(tert-butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-yl ester 
• 146830-36-6 (+)-(1S,4R,4aS,5R,8S,8aR)-5-Acetoxy-1,4,4a,5,8,8a-hexahydro-8-hydroxy-endo-1,4-methanonaphthalene 
• 51175-59-8 norbornenoquinone 
• 864155-65-7 [(1R,2S,5R,6R)-6-Allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid (S)-1-methyl-but-3-enyl ester 
• 864155-66-8 (Z)-(1R,4S,4aR,8S,12aR)-1-(tert-Butyl-dimethyl-silanyloxy)-4-(tert-butyl-diphenyl-silanyloxy)-8-methyl-1,4,4a,5,8,9,12,12a-octahydro-7-oxa-benzocyclodecen-6-one 
• 864155-64-6 [6-allyl-5-(tert-butyl-dimethyl-silanyloxy)-2-(tert-butyl-diphenyl-silanyloxy)-cyclohex-3-enyl]-acetic acid ethyl ester 
• 864155-59-9 (1S,4R,4aS,5R,8S,8aR)-5-Allyl-8-(tert-butyl-dimethyl-silanyloxy)-1,4,4a,5,8,8a-hexahydro-1,4-methano-naphthalen-5-ol 
• 864155-60-2 (1S,4R,4aS,7R,8S,8aR)-7-Allyl-8-(tert-butyl-dimethyl-silanyloxy)-4,4a,6,7,8,8a-hexahydro-1H-1,4-methano-naphthalen-5-one 
• 162662-48-8 (1S,4R,4aS,8S,8aR)-8-(tert-Butyl-dimethyl-silanyloxy)-4,4a,8,8a-tetrahydro-1H-1,4-methano-naphthalen-5-one 
• 157035-24-0 (4S,5R)-5-allyl-4-(tert-butyldimethylsiloxy)cyclohex-2-enone 

Downstream Products

• 864155-68-0 (4S,4aR,8S,12aR)-4-(tert-Butyl-diphenyl-silanyloxy)-8-methyl-decahydro-7-oxa-benzocyclodecene-1,6-dione 
• 864155-69-1 (4S,8aR,12S,12aR)-12-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-4,5,6,7,8,8a,12,12a-octahydro-4-methyl-2H-3-benzoxecin-2,9(1H)-dione 

Relevant academic research and scientific papers

Enantioselective total synthesis of bioactive natural product (+)-Sch 642305: A structurally novel inhibitor of bacterial DNA primase and HIV-1 Tat transactivation

The total synthesis of the bioactive natural product (+)-Sch 642305 has been achieved from a readily available chiral building block using an RCM protocol to construct the key decalactone moiety; our approach is notable for its built-in flexibility and is