86428-51-5

Basic information

• Product Name: 2-(3-methyl-2-cyclohexenyl)propenoate de methyl
• CAS NO: 86428-51-5
• Molecular Weight: 180.247
• Mol File: 86428-51-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2-(3-methyl-2-cyclohexenyl)propenoate de methyl(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-methyl-2-cyclohexenyl)propenoate de methyl(86428-51-5)
• EPA Substance Registry System: 2-(3-methyl-2-cyclohexenyl)propenoate de methyl(86428-51-5)

Safety Data

• Hazardous Substances Data: 86428-51-5(Hazardous Substances Data)

Upstream product

• 23758-27-2 1-methylcyclohex-2-en-1-ol 
• 86428-48-0 (Z,E)-1-fluoro-1-methoxy-2-(phenylsulfinyl)-1-propene 

Relevant articles and documents

NOUVELLE VOIE D'ACCES STEREOSELECTIVE AUX ESTERS ACRYLIQUES SON APPLICATION EN CHIMIE DES SUCRES

Regio- and stereo-selective synthesis of an acryl residue by treatment of an allyl alcohol with (Z,E)-1-fluoro-1-methoxy-2-phenylsulfinylpropene was performed in three consecutive reactions in the same flask; displacement of F- by the alcohol, Claisen rearrengement, and dehydrosulfinylation.Thus, 1,5-anhydro-2-deoxy-4,6-O-isopropylidene-D-arabino-hex-1-enitol gave methyl 3,7-anhydro-6,8-benzylidene-2,4,5-trideoxy-2-C-methylene-D-ribo-oct-4-enonate and methyl 2-O-allyl-4,6-dideoxy-α-D-erythro-hex-4-enopyranoside gave methyl (methyl 2-O-allyl-3,4,6-trideoxy-5-C-methyl-6-C-methylene-α-L-threo-hept-3-enopyranosyd)uronate, which has a chiral quaternary C-5 atom.