86428-48-0

Basic information

• Product Name: Benzene, [(2-fluoro-2-methoxy-1-methylethenyl)sulfinyl]-, (E)-
• CAS NO: 86428-48-0
• Molecular Formula: C10H11FO2S
• Molecular Weight: 214.261
• Mol File: 86428-48-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Benzene, [(2-fluoro-2-methoxy-1-methylethenyl)sulfinyl]-, (E)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(2-fluoro-2-methoxy-1-methylethenyl)sulfinyl]-, (E)-(86428-48-0)
• EPA Substance Registry System: Benzene, [(2-fluoro-2-methoxy-1-methylethenyl)sulfinyl]-, (E)-(86428-48-0)

Safety Data

• Hazardous Substances Data: 86428-48-0(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 86440-79-1 (R*,R*,R*,S*)-2,2,2-trifluoro-1-methylethyl phenyl sulfoxide 
• 98120-52-6 1,1,1-trifluoro-2-phenylthiopropane 

Downstream Products

• 69637-66-7 2-(2-cyclohexenyl)-2-propenoic methylester 
• 86428-50-4 2-(2-cyclohexen-1-ylidenel)propanoate de methyle 
• 86428-53-7 2-(1-methyl-2-cyclohexenyl)propenoate de methyle 
• 86428-51-5 2-(3-methyl-2-cyclohexenyl)propenoate de methyl 
• 86428-52-6 (Z,E)-2-(3-methyl-2-cyclohexen-1-ylidene)propanoate de methyl 
• 73421-20-2 2-methylene-3-phenyl-4-pentenoate de methyle 
• 86428-49-1 2-methyl-3-phenyl-2,4-pentadienoate de methyle 

Relevant articles and documents

NOUVELLE VOIE D'ACCES STEREOSELECTIVE AUX ESTERS ACRYLIQUES SON APPLICATION EN CHIMIE DES SUCRES

Regio- and stereo-selective synthesis of an acryl residue by treatment of an allyl alcohol with (Z,E)-1-fluoro-1-methoxy-2-phenylsulfinylpropene was performed in three consecutive reactions in the same flask; displacement of F- by the alcohol, Claisen rearrengement, and dehydrosulfinylation.Thus, 1,5-anhydro-2-deoxy-4,6-O-isopropylidene-D-arabino-hex-1-enitol gave methyl 3,7-anhydro-6,8-benzylidene-2,4,5-trideoxy-2-C-methylene-D-ribo-oct-4-enonate and methyl 2-O-allyl-4,6-dideoxy-α-D-erythro-hex-4-enopyranoside gave methyl (methyl 2-O-allyl-3,4,6-trideoxy-5-C-methyl-6-C-methylene-α-L-threo-hept-3-enopyranosyd)uronate, which has a chiral quaternary C-5 atom.