864296-83-3

Basic information

• Product Name: methyl 3-chloro-4-nitrosobenzoate
• Synonyms: methyl 3-chloro-4-nitrosobenzoate
• CAS NO: 864296-83-3
• Molecular Weight: 199.594
• Mol File: 864296-83-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 3-chloro-4-nitrosobenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-chloro-4-nitrosobenzoate(864296-83-3)
• EPA Substance Registry System: methyl 3-chloro-4-nitrosobenzoate(864296-83-3)

Safety Data

• Hazardous Substances Data: 864296-83-3(Hazardous Substances Data)

Upstream product

• 13170-28-0 methyl p-nitrosobenzoate 
• 7664-93-9 sulfuric acid 
• 84228-44-4 methyl 4-amino-3-chlorobenzoate 

Downstream Products

• 864296-84-4 3-chloro-4-(3,6-dihydro-[1,2]oxazin-2-yl)-benzoic acid methyl ester 

Relevant articles and documents

Para-Selective Halogenation of Nitrosoarenes with Copper(II) Halides

The para-selective direct bromination and chlorination of nitrosoarenes with copper(II) bromide and chloride is reported. Under mild reaction conditions, a range of halogenated arylnitroso compounds are obtained in moderate to good yields with high regioselectivity. Additionally, the versatility of the method is demonstrated by the development of a one-pot procedure to obtain the corresponding para-halogenated aniline- and nitrobenzene derivatives.