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Benzenemethanol, 2-chloro-α-ethynyl-α-phenyl-, (R)-, also known as (R)-2-chloro-1-(2-phenylethynyl)benzene-1-methanol, is a chiral organic compound with the molecular formula C14H11ClO. It is a derivative of benzenemethanol, featuring a chloro group at the 2-position, an ethynyl group at the α-position, and a phenyl group at the α-position. Benzenemethanol, 2-chloro-a-ethynyl-a-phenyl-, (R)- is characterized by its asymmetric carbon atom, which gives rise to two enantiomers, (R)- and (S)-. The (R)-enantiomer is the focus of this summary. It is an important intermediate in the synthesis of various pharmaceuticals and agrochemicals, particularly those with chiral centers. The compound's unique structure and properties make it valuable in the development of enantioselective synthesis methods and the production of enantiomerically pure compounds.

86436-15-9

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86436-15-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86436-15-9 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,4,3 and 6 respectively; the second part has 2 digits, 1 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 86436-15:
(7*8)+(6*6)+(5*4)+(4*3)+(3*6)+(2*1)+(1*5)=149
149 % 10 = 9
So 86436-15-9 is a valid CAS Registry Number.

86436-15-9SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (S)-(-)-1-(o-chlorophenyl)-1-phenyl-2-propyn-1-ol

1.2 Other means of identification

Product number -
Other names (R)-1-(2-chlorophenyl)-1-phenylprop-2-yn-1-ol

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:86436-15-9 SDS

86436-15-9Relevant academic research and scientific papers

Chiral Recognition in Complexes of Tertiary Acetylenic Alcohols and Sparteine; Mutual Optical Resolution by Complex Formation

Toda, Fumio,Tanaka, Koichi,Ueda, Hideo,Oshima, Tokio

, p. 743 - 744 (1983)

Tertiary acetylenic alcohols have been resolved efficiently by complex formation with (-)-sparteine, and (+/-)-sparteine was resolved by complex formation with the optically active tertiary acetylenic alcohols; an X-ray structural study of the 1:1 complex of 1-(o-bromophenyl)-1-phenylprop-2-ynol (1d) and (-)-sparteine showed that two hydrogen bonds, CC-H...OH and OH...N, are important in formation of the complex.

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