Journal of the Chemical Society. Chemical communications p. 743 - 744 (1983)
Update date:2022-08-03
Topics:
Toda, Fumio
Tanaka, Koichi
Ueda, Hideo
Oshima, Tokio
Tertiary acetylenic alcohols have been resolved efficiently by complex formation with (-)-sparteine, and (+/-)-sparteine was resolved by complex formation with the optically active tertiary acetylenic alcohols; an X-ray structural study of the 1:1 complex of 1-(o-bromophenyl)-1-phenylprop-2-ynol (1d) and (-)-sparteine showed that two hydrogen bonds, CC-H...OH and OH...N, are important in formation of the complex.
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Doi:10.1515/znb-2004-11-1215
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