864430-41-1

Upstream product

• 864430-38-6 (E)-(S)-1-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-octadec-4-en-3-one 
• 864430-39-7 (E)-(2S,3S)-1-(tert-Butyl-diphenyl-silanyloxy)-2,4-dimethyl-octadec-4-en-3-ol 
• 851121-38-5 [4-(tert-butyl-diphenyl-silanyloxy)-1,3-dimethyl-2-oxo-butyl]-phosphonic acid diethyl ester 
• 864430-40-0 (1S,2S)-3-(tert-Butyl-diphenyl-silanyloxy)-2-methyl-1-((2R,3R)-2-methyl-3-tridecyl-oxiranyl)-propan-1-ol 

Downstream Products

• 864430-45-5 (S)-3-Benzyloxy-2-((2S,3R)-3-benzyloxy-2-{(S)-3-methyl-2-[(R)-2-((4R,5S,6R)-2,2,5-trimethyl-6-tridecyl-[1,3]dioxan-4-yl)-propionylamino]-butyrylamino}-butyrylamino)-propionic acid allyl ester 
• 452956-91-1 prop-2-en-1-yl (2S)-3-(benzyloxy)-2-{[(2S)-3-(benzyloxy)-2-{[(2S)-2-{[(2R,3R,4S,5R)-3,5-dihydroxy-2,4-dimethyloctadecanoyl]amino}-3-methylbutanoyl]amino}butanoyl]amino}propanoate 
• 452956-92-2 (2S)-3-(benzyloxy)-2-{[(2S)-3-(benzyloxy)-2-{[(2S)-2-{[(2R,3R,4S,5R)-3,5-dihydroxy-2,4-dimethyloctadecanoyl]amino}-3-methylbutanoyl]amino}butanoyl]amino}propanoic acid 
• 864430-44-4 (S)-3-Benzyloxy-2-((2S,3R)-3-benzyloxy-2-{(S)-3-methyl-2-[(R)-2-((4R,5S,6R)-2,2,5-trimethyl-6-tridecyl-[1,3]dioxan-4-yl)-propionylamino]-butyrylamino}-butyrylamino)-propionic acid methyl ester 

Relevant academic research and scientific papers

Total synthesis of stevastelin B3

The total synthesis of stevastelin B3 was achieved using, as a key step, a method developed by us for the synthesis of 2-methyl-1,3-diols by Ti(III)-mediated diastereo- and regioselective opening of trisubstituted 2,3-epoxy alcohols, to carry out the ster