86448-63-7

Upstream product

• 78549-08-3 (1S,2S,3S)-1-phenyl-2-p-tolylthio-2-p-tolylsulphinylethanol 
• 59532-35-3 (+)-(S)-4-Methylphenyl 4-methylphenylthiomethyl sulfoxide 
• 100-52-7 benzaldehyde 
• 89921-65-3 (1S,2R,3S)-1-phenyl-2-p-tolylthio-2-p-tolylsulphinylethanol 

Relevant academic research and scientific papers

Asymmetric Synthesis of Protected α-Hydroxyaldehydes via Reduction of α-Arylthio-β-oxosulphoxides

The complex metal hydride reduction of α-arylthio-β-oxosulphoxides to the corresponding alcohols is highly stereospecific.The stereochemical course of the reaction has been determined and a detailed examination of the factors responsible for the stereospe

AN EFFICIENT 1,3-ASYMMETRIC INDUCTION ACCOMPANIED WITH EPIMERIZATION AT THE 2-POSITION. STEREOSELECTIVE REDUCTION OF α-SUBSTITUTED β-KETO SULFOXIDES UNDER BASIC CONDITIONS

An efficient 1,3-asymmetric induction was realized in the reduction of β-keto sulfoxides having various α-substituents with NaBH4 under basic conditions and, by the application of this induction, (R)-α-acetoxyphenylacetaldehyde was synthesized.