864536-04-9

Basic information

• Product Name: 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol
• Synonyms: 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol
• CAS NO: 864536-04-9
• Molecular Weight: 562.88
• Mol File: 864536-04-9.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol(864536-04-9)
• EPA Substance Registry System: 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol(864536-04-9)

Safety Data

• Hazardous Substances Data: 864536-04-9(Hazardous Substances Data)

Upstream product

• 438588-60-4 2-((1R,2R)-2-aminocyclohexyl)isoindoline-1,3-dione 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 
• 220044-28-0 N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine 
• 191480-63-4 (1R,2R)-1,2-diaminocyclohexane monohydrochloride 
• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 864536-03-8 tert-butyl N-[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methyl]amino}cyclohexyl]carbamate 
• 1067549-91-0 2-({[(1R,2R)-2-aminocyclohexyl]amino}methyl)-4,6-di-tert-butylphenol 

Relevant articles and documents

Effect of ligand N,N-substituents on the reactivity of chiral copper(II) salalen, salan, and salalan complexes toward asymmetric nitroaldol reactions

The synthesis and effect of ligand N,N-substituents on the reactivity of chiral copper(II) salalen, salan, and salalan complexes toward nitroaldol reactions of nitromethane with various aldehydes have been described. The salan complexes exhibit superior results compared to the salalen and salalan complexes; the nature of the N,N-substituents is crucial for the enantioselectivity of the target nitroaldol products.

Synthesis of an optically active al(salalen) complex and its application to catalytic hydrophosphonylation of aldehydes and aldimines

Optically active aluminum(salalen) complex 2 was newly synthesized in a modular synthetic manner, and it was found to serve as an efficient catalyst for hydrophosphonylation of aldehydes and aldimines, giving the corresponding α-hydroxy and α-amino phosph