220044-28-0

Basic information

• Product Name: N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine
• Synonyms: N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine
• CAS NO: 220044-28-0
• Molecular Weight: 330.514
• Mol File: 220044-28-0.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine(220044-28-0)
• EPA Substance Registry System: N-(2-hydroxy-3,5-di-tert-butylbenzaldehyde)-1-amino-2-cyclohexaneimine(220044-28-0)

Safety Data

• Hazardous Substances Data: 220044-28-0(Hazardous Substances Data)

Upstream product

• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 20439-47-8 (1R,2R)-1,2-diaminocyclohexane 
• 191480-63-4 (1R,2R)-1,2-diaminocyclohexane monohydrochloride 
• 116407-32-0 (1R,2R)-(-)-1,2-diammoniumcyclohexane mono-L-(+)-tartrate 

Downstream Products

• 446023-31-0 C₃₃H₄₇ClN₂O₂ 
• 864536-04-9 2,4-di-tert-butyl-6-((E)-(((1R,2R)-2-((3,5-di-tert-butyl-2-hydroxybenzyl)(methyl)amino)cyclohexyl)imino)methyl)phenol 
• 864536-03-8 tert-butyl N-[(1R,2R)-2-{[(3,5-di-tert-butyl-2-hydroxyphenyl)methyl]amino}cyclohexyl]carbamate 
• 1067549-91-0 2-({[(1R,2R)-2-aminocyclohexyl]amino}methyl)-4,6-di-tert-butylphenol 

Relevant articles and documents

Dimeric chiral Mn(III) Schiff base complex-catalysed enantioselective epoxidation of non-functionalised alkenes

Dimeric chiral Mn(III) Schiff base complex 1 has been investigated as a catalyst for enantioselective epoxidation of chromenes, indene and styrene with an objective to explore its efficiency and recycling capability. Excellent conversions were obtained wi

Synthesis of an optically active al(salalen) complex and its application to catalytic hydrophosphonylation of aldehydes and aldimines

Optically active aluminum(salalen) complex 2 was newly synthesized in a modular synthetic manner, and it was found to serve as an efficient catalyst for hydrophosphonylation of aldehydes and aldimines, giving the corresponding α-hydroxy and α-amino phosph

Novel chiral (salen)MnIII complexes containing a calix[4]arene unit as catalysts for enantioselective epoxidation reactions of (Z)-aryl alkenes

New asymmetric (salen)MnIII and UO2 complexes containing a calix[4]arene unit in the ligand framework were synthesized. The UO2 complexes were characterized by 1H-, 13C-, 2D TOCSY and T-ROESY NMR spectroscopy. Furthermore, the structure of one UO 2 complex was determined by single-crystal X-ray analysis. The data showed that UO2 complexes, which can be considered in first approximation models of the Mn=O oxidant active species, possess a chiral pocket and adopt relevant conformations for the selectivity of the oxygen transfer process. Epoxidation data of model alkenes with the MnIII complexes showed moderate ee values and were not conclusive in indicating that the calix[4]arene unit might be able to influence the selectivity by a molecular recognition mechanism. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.