86459-80-5Relevant academic research and scientific papers
Alkyl Migration in Competition with Phenylthio Migration in the Acid-catalysed Rearrangement of Alcohols
Hannaby, Malcolm,Warren, Stuart
, p. 3007 - 3014 (2007/10/02)
Sulfonate derivatives of conformationally rigid syn-2-phenylthiocyclohexanols, which are prevented from phenylthio migration by stereochemistry, rearrange slowly by alkyl migration or ring contraction.In contrast to other electronegative groups, phenylthio slows the reaction down but allows migration of other groups.
REGIOSPECIFIC PREPARATION OF THERMODYNAMIC SILYL ENOL ETHERS USING BROMOMAGNESIUM DIALKYLAMIDES
Krafft, M. E.,Holton, Robert A.
, p. 1345 - 1348 (2007/10/02)
Thermodynamic silyl enol ethers are regiospecifically generated in high yield from cyclic ketones, bromomagnesium diisopropylamide (BMDA) and trimethylsilyl chloride.
Stereochemical studies. X. Synthesis of some epimeric δ-lactones
Cooke, Ellen,Paradellis, Themistocles C.,Edward John T.
, p. 29 - 34 (2007/10/02)
Stereospecific synthesis are reported for the δ-lactones 3, 5, 8, 17, and 26.
