864629-04-9Relevant academic research and scientific papers
N -acyliminoimidazolium ylides as precursors to anionic N -heterocyclic carbene ligands: Control of topology and reactivity
Guernon, Hannah,Legault, Claude Y.
, p. 1988 - 1994 (2013/05/09)
A family of N-heterocyclic carbene ligands based on N-acyl iminoimidazolium ylides has been developed and investigated. The ylides are stable and are easily obtained in two steps. Following deprotonation, they form bidentate anionic NHC ligands. The synth
Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex
Legault, Claude Y.,Kendall, Christopher,Charette, Andre B.
, p. 3826 - 3828 (2007/10/03)
The efficient synthesis of a N-benzoyliminoimidazolium ylide provides access to a new type of N-heterocyclic anionic carbene, from which air stable Ag(I) and Cu(II) complexes and a catalytically active Rh(I) complex were formed. The Royal Society of Chemi
