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(E)-1-Phenyl-4-(2-trimethylsilanyl-ethyl)-hexa-3,5-dien-1-ol is a complex organic compound with the molecular formula C19H28OSi. It is characterized by a phenyl group attached to a hexa-3,5-dien-1-ol backbone, with a 2-trimethylsilanyl-ethyl substituent at the 4-position. (E)-1-Phenyl-4-(2-trimethylsilanyl-ethyl)-hexa-3,5-dien-1-ol is known for its unique structure, which includes a conjugated diene system and a silyl ether group. It is often used in organic synthesis, particularly in reactions where the silyl group can be used to protect or modify functional groups. The compound's properties, such as its reactivity and stability, make it a valuable intermediate in the synthesis of more complex molecules.

86486-98-8

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86486-98-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 86486-98-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,6,4,8 and 6 respectively; the second part has 2 digits, 9 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 86486-98:
(7*8)+(6*6)+(5*4)+(4*8)+(3*6)+(2*9)+(1*8)=188
188 % 10 = 8
So 86486-98-8 is a valid CAS Registry Number.

86486-98-8Downstream Products

86486-98-8Relevant academic research and scientific papers

INTRAMOLACULAR DIELS-ALDER REACTIONS OF SILICON SUBSTITUED DIENES.SYNTHESIS WITH HOMO-ALLYL SILANES.

Wilson, Stephen R.,Shedrinsky, Alexander,Serajul Haque, M.

, p. 895 - 904 (1983)

Metallation of 3-vinyl-5-trimethylsilyl-1-pentene (16) with n-BuLi gives a Si substitued pentadienyl anion reagent for bisannelation of ortho-alkenyl benzaldehydes.Tricyclic olefin 23b produced by this method is a homo-allylsilane which undergoes protodesylilation to 4-vinyl-12-methoxy-18,19-bisnor-podocarpa-8,11,13-triene 24b.The addition of β-(trimethylsylil)ethyl magnesium bromide (12) to 12-methoxy-18,19-bisnor-5β-podocarpa-8,11,13-triene-4-one 27 gave the corresponding alcohol 29.When 29 and related γ-hydroxy silanes are treated with acid, dehydratation to allylsilane and protodesilylation to exocyclic vinyl compounds result.Alcohol 29 produces 24b in 93percent yield.Compound 24b can be converted in several steps to podocarpic acid.

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