86488-93-9

Upstream product

• 89358-53-2 (1R*,2R*)-2-Diphenylphosphinoylmethylcyclohexanol 
• 89358-81-6 1-(Diphenyl-phosphinoylmethyl)-cyclohexane-1,2-diol 
• 42036-65-7 2-dimethylaminomethylcyclohexanone hydrochloride 
• 4559-70-0 Diphenylphosphine oxide 
• 87512-44-5 1-(diphenylphosphinoylmethyl)-7-oxabicyclo<4.1.0>heptane 
• 76002-40-9 1-(diphenylphosphinoylmethyl)cyclohexene 
• 2129-89-7 diphenyl(methyl)phosphine oxide 
• 87512-43-4 1-(diphenylphosphinoylmethyl)cyclohexanol 
• 108-94-1 cyclohexanone 
• 286-20-4 cyclohexane-1,2-epoxide 
• 21430-12-6 6-heptenoyl chloride 
• 1119-60-4 hept-6-enoic acid 
• 869483-27-2 1-(diphenyl-phosphinoyl)-hept-6-en-1-one 

Downstream Products

• 86488-96-2 α-<(diphenylphosphinyl)methyl>-ε-caprolactam 
• 86488-95-1 2-<(diphenylphosphinyl)methyl>cyclohexanone oxime 

Relevant academic research and scientific papers

Radical cyclizations of alkenyl acylphosphonate derivatives under thermal and photochemical conditions

The use of alkenyl acylphosphonate and acylphosphine oxide derivatives as acceptors in radical cyclizations was studied under thermal and photochemical conditions, respectively. The cyclizations of alkenyl acylphosphonates under thermal conditions occurre

Synthesis of β-(Diphenylphosphinoyl) Ketones

The title compounds may be made by addition of phosphorus nucleophiles (Ph2PO-, Ph2POMgX, Ph2PCl) to enones, by addition of phosphorus-stabilised carbanions to a α-carbonyl cation equivalents (2,3-dichloropropene, epoxides, and α-MeO-ketones) and by oxidation of allyl diphenylphosphine oxides.