87512-44-5Relevant academic research and scientific papers
Synthesis of β-(Diphenylphosphinoyl) Ketones
Bell, Andrew,Davidson, Alan H.,Earnshaw, Chris,Norrish, Howard K.,Torr, Richard S.,et al.
, p. 2879 - 2892 (2007/10/02)
The title compounds may be made by addition of phosphorus nucleophiles (Ph2PO-, Ph2POMgX, Ph2PCl) to enones, by addition of phosphorus-stabilised carbanions to a α-carbonyl cation equivalents (2,3-dichloropropene, epoxides, and α-MeO-ketones) and by oxidation of allyl diphenylphosphine oxides.
Synthesis of an Unstable Allyl Sulphide from an Allyl Phosphine Oxide
Torr, Richard S.,Warren, Stuart
, p. 1169 - 1172 (2007/10/02)
The epoxide (8) reacts with PhSLi to give Horner-Wittig intermediate (9) and hence the allyl sulphide (10).The stereochemistry and reactions of the intermediates are described.
