864913-65-5

Basic information

• Product Name: 2-chloro-6-(4-methylphenyl)pyridine
• Synonyms: 2-chloro-6-(4-methylphenyl)pyridine
• CAS NO: 864913-65-5
• Molecular Weight: 203.671
• Mol File: 864913-65-5.mol

Chemical Properties

• CAS DataBase Reference: 2-chloro-6-(4-methylphenyl)pyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-6-(4-methylphenyl)pyridine(864913-65-5)
• EPA Substance Registry System: 2-chloro-6-(4-methylphenyl)pyridine(864913-65-5)

Safety Data

• Hazardous Substances Data: 864913-65-5(Hazardous Substances Data)

Upstream product

• 106-38-7 para-bromotoluene 
• 652148-92-0 2-chloro-6-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine 
• 109-09-1 2-chloropyridine 
• 459-44-9 4-methylbenzenediazonium tetrafluoroborate 
• 18412-57-2 p-tolyltriethoxysilane 
• 258506-66-0 2-chloro-5-iodo-pyridine 
• 2402-78-0 2,6-dichloropyridine 
• 5720-05-8 4-methylphenylboronic acid 

Downstream Products

• 864913-66-6 2-(4-bromomethyl-phenyl)-6-chloro-pyridine 

Relevant articles and documents

Perylenequinonoid-catalyzed photoredox activation for the direct arylation of (het)arenes with sunlight

Naturally occurring perylenequinonoid pigments (PQPs) have attracted considerable attention owing to their excellent properties of photosensitization. They have been widely investigated as an aspect of photophysics and photobiology. However, their applications in photocatalysis are yet to be explored. We report here that sunlight along with 1 mol% cercosporin, which is one of the perylenequinonoid pigments, catalyzes the direct C-H bond arylation of (het)arenes by a photoredox process with good regioselectivity and broad functional group compatibility. Furthermore, a gram-scale reaction with great conversions of substrates was achieved even by a cercosporin-containing supernatant without organic solvent extraction and purification after liquid fermentation. Thus we set up a bridge between microbial fermentation and organic photocatalysis for chemical reactions in a sustainable, environmentally friendly manner.

Copper-catalyzed Hiyama coupling of (hetero)aryltriethoxysilanes with (hetero)aryl iodides

A CuI-catalyzed Hiyama coupling was achieved, which proceeds in the absence of an ancillary ligand for aryl-heteroaryl and heteroaryl-heteroaryl couplings. A P,N-ligand is required to obtain the best product yields for aryl-aryl couplings. In addition to facilitating transmetalation, CsF is also found to function as a stabilizer of the [CuAr] species, potentially generated as an intermediate after transmetalation of aryltriethoxysilanes with Cu I-catalysts in the absence of ancillary ligands.

Palladium-catalyzed Suzuki-Miyaura coupling of pyridyl-2-boronic esters with aryl halides using highly active and air-stable phosphine chloride and oxide ligands

(Chemical Equation Presented) The palladium-catalyzed Suzuki-Miyaura coupling of pyridyl-2-boronic esters provided an efficient approach to useful biaryl building blocks containing a 2-pyridyl moiety. The convenient reaction protocol demonstrates its pote

BASIC AMINE COMPOUND AND USE THEREOF

Novel amine compounds which are represented by the following formula (1) and efficacious against diseases such as a viral infectious disease with HIV, rheumatism, and cancer metastasis; typically, A 1 and A 2 represent a hydrogen atom or a substitutable monocyclic or polycyclic heteroaromatic ring and W represents a substitutable benzene ring or any group represented by the following formula (10) or (11): where X represents O, CH 2 , C(=O), NR 11 , or CHR 35 and D represents a group represented by the following formula (6): where Q represents a single bond, NR 12 , or a group represented by the formula (13): and Y represents a group represented by the following formula (7) : where z represents a substitutable monocyclic or polycyclic aromatic ring; and B represents -NR 25 R 26 ; and R 1 to R 26 in the above formulae represent a hydrogen atom, an alkyl group, an alkenyl group, or an alkynyl group.