864971-69-7

Upstream product

• 123-54-6 acetylacetone 
• 91110-24-6 Acetic acid (2S,3R,4R,5R)-3,4-bis-benzyloxy-5-benzyloxymethyl-tetrahydro-furan-2-yl ester 
• 16838-89-4 2,3,5-tri-O-benzyl-D-ribofuranose 
• 64363-77-5 methyl 2,3,5-tri-O-benzyl-D-ribofuranoside 
• 100-39-0 benzyl bromide 

Relevant academic research and scientific papers

Method for preparing beta-diketone C-nucleoside

The invention provides a method for preparing beta-diketone C-nucleoside. The method utilizes anomeric hydroxyl exposed sugar 1 and beta-diketone 2 to directly generate beta-diketone C-nucleoside compound 3 under the catalysis of Lewis acid, wherein the r

Sc(OTf)3-catalyzed C-glycosylation of β-diketones. A facile access to useful precursors of heteroaromatic C-glycosides

Scandium tris(triflate) efficiently catalyzes C-glycosylation of β-diketones with glycosyl acetate. Elaboration of the β-diketo moiety in the resulting C-glycosides to heterocycles provides a flexible route to the C-nucleoside analogs.