86504-35-0

Upstream product

• 201230-82-2 carbon monoxide 
• 6485-40-1 (R)-Carvone 
• 131569-57-8 (E)-3-[(1R,4R)-4-Methyl-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-but-2-enoic acid methyl ester 
• 131569-58-9 3-[(1R,4R)-4-Methyl-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-butyric acid methyl ester 
• 38049-24-0 1-[(1R,4R)-4-Methyl-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-ethanone 
• 38049-25-1 2-((2R,5R)-5-Isopropenyl-2-methyl-cyclohexyloxy)-tetrahydro-pyran 
• 131569-59-0 3-[(1R,4R)-4-Methyl-3-(tetrahydro-pyran-2-yloxy)-cyclohexyl]-butan-1-ol 
• 5524-05-0 (2R,5R)-5-isopropenyl-2-methylcyclohexanone 
• 3792-53-8 2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 5524-05-0 (+)-dihydrocarvone 

Relevant academic research and scientific papers

Rh-catalyzed selective synthesis of 1,5-dimethylhexahydro-1H-inden-4(2H)-one via hydroformylation of (R)-carvone

This work reports domino hydroformylation, hydrogenation and intramolecular keto-aldol condensation reactions for the selective synthesis of 1,5-dimethylhexahydro-1H-inden-4(2H)-one obtained from (R)-carvone and dihydrocarvone under homogeneous hydroformy

Studies on the Liverwort Sesquiterpene Alcohol Tamariscol. Synthesis and Absolute Configuration

The relative configuration of the liverwort sesquiterpene alcohol (-)-tamariscol 1 has been confirmed by total synthesis and the absolute configuration has been established from the CD spectrum of the hydrindanone degradation product from (-)-1.

Absolute Configuration and Synthesis of the Liverwort Sesquiterpene Alcohol Tamariscol

The relative configuration of the liverwort sesquiterpene alcohol (-)-tamariscol (1) has been confirmed by total synthesis and its absolute configuration has been established from the CD spectrum of the hydrindanone degraded from (-)-(1).

Hydroformylation of chiral terpenes with PtCl(SnCl3)-(bis-phosphine) as catalyst

(+)-R-Limonene and (-)-R-carvone undergo hydroformylation in the presence of catalytic Pt-bisphosphine-SnCl2 systems to yield exclusively the linear products.The internal double bond and the carbonyl group remain intact in both substrates during the react

Cyclic keto-butyraldehydes a process for their preparation, and their use in the preparation of cyclic diisocyanates

New cyclic keto-butyraldehydes of the formula STR1 in which R1 and R2 are either identical or different and denote hydrogen or lower alkyl and in which the cycloaliphatic ring may contain a double bond, can be prepared from the corre