865288-85-3Relevant academic research and scientific papers
Relaying asymmetry of transient atropisomers of o-iodoanilides by radical cyclizations
Petit, Marc,Lapierre, Andre J. B.,Curran, Dennis P.
, p. 14994 - 14995 (2007/10/03)
Atropisomers of N-2°-alkyl-N-acryloyl-2-iodoanlides have been resolved by chromatography and crystallization-induced asymmetric transformation. These molecules have atropisomerization barriers of 23-24 kcal/mol and return to equilibrium ratios over severa
