86534-19-2

Basic information

• Product Name: (4aR,6S,6aS,22aS,22bR)-6-Methoxy-10,19-dimethyl-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene
• Synonyms: (4aR,6S,6aS,22aS,22bR)-6-Methoxy-10,19-dimethyl-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene
• CAS NO: 86534-19-2
• Molecular Weight: 510.628
• Mol File: 86534-19-2.mol

Chemical Properties

• CAS DataBase Reference: (4aR,6S,6aS,22aS,22bR)-6-Methoxy-10,19-dimethyl-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene(CAS DataBase Reference)
• NIST Chemistry Reference: (4aR,6S,6aS,22aS,22bR)-6-Methoxy-10,19-dimethyl-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene(86534-19-2)
• EPA Substance Registry System: (4aR,6S,6aS,22aS,22bR)-6-Methoxy-10,19-dimethyl-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene(86534-19-2)

Safety Data

• Hazardous Substances Data: 86534-19-2(Hazardous Substances Data)

Upstream product

• 86534-15-8 methyl 4,6-O-benzylidene-2,3-O-bis(t-butyl-oxycarbonylmethyl)-α-D-mannopyranoside 
• 86534-17-0 methyl 4,6-O-benzylidene-2,3-O-bis(p-toluenesulphonyloxyethyl)-α-D-mannopyranoside 
• 86534-16-9 2-[(4aR,6S,7S,8S,8aR)-7-(2-Hydroxy-ethoxy)-6-methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yloxy]-ethanol 
• 4148-58-7 (4aR,6S,7S,8R,8aS)-6-Methoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol 
• 86545-48-4 (4aR,6S,6aS,22aS,22bR)-6-Methoxy-2-phenyl-hexadecahydro-1,3,5,7,13,16,22-heptaoxa-10,19-diaza-cyclooctadeca[a]naphthalene-10,19-dicarboxylic acid diethyl ester 

Downstream Products

• 88877-48-9 C₂₈H₄₄N₂O₉ 
• 88877-45-6 C₃₀H₅₀N₂O₉⁽²⁺⁾*2I^(1-) 

Relevant articles and documents

SYNTHESIS OF CHIRAL DIAZA-CROWN ETHERS INCORPORATING CARBOHYDRATE UNITS

A synthesis of a novel chiral diaza crown ethers derived from α-D-glucose, α-D-mannose, and α-D-galactose in two alternative pathways is described.

Synthesis of Novel Chiral Macrocyclic Ligands bearing Methyl 4,6-O-Benzylidene-α-D-mannopyranoside

O-Alkylation of methyl 4,6-O-benzylidene-α-D-mannopyranoside with t-butyl bromoacetate under phase-transfer conditions, followed by reduction and tosylation leads to an intermediate which was used in the formation of the two diaza-crown ethers (3a) and (3