86535-06-0

Upstream product

• 59005-41-3 (S)-4-Benzyloxy-3-methyl-butane-1,2-diol 
• 98-59-9 p-toluenesulfonyl chloride 
• 86562-30-3 (2R,3R)-dimethyl threo-3-methylmalate THP ether 
• 13398-40-8 (2R,3R)-threo-β-methylmalic acid 
• 86562-31-4 (2R,3S)-threo-3-methylbutane-1,2,4-triol 2-THP ether 
• 71565-21-4 (2S,4'R)-(+)-2-(2,2-Dimethyl-1,3-dioxolan-4-yl)-1-propanol 
• 77333-26-7 (2R,3S)-threo-3-methylbutane-1,2,4-triol 
• 86562-32-5 (2R,3S)-threo-3-methylbutane-1,2,4-triol 1,2-acetonide 4-benzyl ether 
• 77398-86-8 dimethyl (2R,3R)-2-hydroxy-3-methylsuccinate 
• 642-92-2 D,L-threo-β-methylaspartic acid 
• 86562-29-0 (2R,3R)-(-)-threo-3-methylaspartic acid 
• 81422-90-4 (2R,3S)-threo-3-methylbutane-1,2,4-triol 4-benzyl ether 

Downstream Products

• 81380-12-3 (2S,3R)-3,4-epoxy-2-methyl-1-butanol benzyl ether 
• 72598-35-7 (-)-serricornin 
• 72485-37-1 (4R,6S,7S)-7-acetoxy-4,6-dimethyl-3-nonanone 
• 82335-98-6 serricornin acetate <(4S,6R,7R)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 149-31-5 (2S,3S)-2-methylpentane-1,3-diol 
• 83997-86-8 serricornin acetate <(4S,6S,7S)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 86535-07-1 (2S,3S)-threo-2-methylpentane-1,3-diol 1-benzyl ether 
• 86535-08-2 (2S,3S)-threo-2-methylpentane-1,3-diol 1-benzyl ether 3-THP ether 
• 86535-14-0 (2S,3S)-2-methyl-1-(4-methylbenzenesulfonyloxy)-3-pentanol 
• 86535-10-6 (2S,3S)-threo-2-methylpentane-1,3-diol 3-THP ether 1-tosylate 

Relevant academic research and scientific papers

THE NITRO-ALDOL REACTION OF α-KETOALDEHYDES WITH NITROALKANES YIELDS α-DIKETONES

The reaction of α-ketoaldehydes with nitroalkanes at pH 9 yields nitro-aldols, which eliminate nitrite to form α-diketones.

SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY OF SERRICORNIN

The absolute stereochemistry of serricornin (4,6-dimethyl-7-hydroxy-3-nonanone) was established as 4S, 6S, 7S by synthesizing both (4S, 6S, 7S)-isomer and its antipode.Only the natural enantiomer was bioactive.by