59005-41-3

Upstream product

• 87172-27-8 cis-4-benzyloxy-2,3-epoxy-1-butanol 
• 15681-48-8 lithium dimethylcuprate 
• 100-39-0 benzyl bromide 
• 57280-24-7 (R)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propan-1-ol 
• 1184-53-8 methylcopper 

Downstream Products

• 78433-56-4 (R)-2-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane 
• 95532-13-1 2,2-Dimethyl-propionic acid (2R,3S)-4-benzyloxy-2-hydroxy-3-methyl-butyl ester 
• 78433-55-3 Toluene-4-sulfonic acid (S)-4-benzyloxy-2-hydroxy-3-methyl-butyl ester 
• 130740-38-4 (E)-(2S,4S,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-38-4 (E)-(2S,4R,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undec-7-ene-1,4-diol 
• 130740-50-0 (R)-2-[(2R,3S)-3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 
• 130740-50-0 (R)-2-[3-((E)-(1R,2S,5R,6S)-7-Benzyloxy-1-methoxy-5-methoxymethoxy-2,4,6-trimethyl-hept-3-enyl)-oxiranyl]-propan-1-ol 
• 116233-37-5 2-[(E)-1-((1R,2S)-3-Benzyloxy-1-methoxymethoxy-2-methyl-propyl)-1-methyl-but-2-enyloxymethyl]-4,4-dimethyl-4,5-dihydro-oxazole 
• 130740-49-7 (3E,7E)-(2S,5S,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-2,6,8,10-tetramethyl-undeca-3,7-dien-1-ol 
• 116233-42-2 (E)-(1R,2S,5R,6S)-7-Benzyloxy-1-(4,4-dimethyl-4,5-dihydro-oxazol-2-yl)-5-methoxymethoxy-2,4,6-trimethyl-hept-3-en-1-ol 
• 130766-31-3 (2Z,7E)-(4R,5R,6S,9R,10S)-11-Benzyloxy-5-methoxy-9-methoxymethoxy-6,8,10-trimethyl-undeca-2,7-dien-4-ol 
• 130740-47-5 (E)-(2R,3S,6R,7S)-8-Benzyloxy-2-methoxy-6-methoxymethoxy-3,5,7-trimethyl-oct-4-en-1-ol 
• 130740-46-4 (5S,6R)-7-Benzyloxy-5-methoxymethoxy-6-methyl-hept-2-yn-4-one 
• 116233-41-1 (E)-(5R,6S)-7-Benzyloxy-5-methoxymethoxy-4,6-dimethyl-hept-2-en-4-ol 

Relevant academic research and scientific papers

Isomer Selectivity in Stereocontrolled Payne Rearrangement-epoxide Cleavage of 2,3-Epoxy Alcohols in Aprotic Solvents: Application to an Enantioselective Total Synthesis of (+)-exo-Brevicomin

Organo-copper and -cuprate reagents may be used to trap the more reactive epoxy alkoxide isomer in a Lewis acid-catalysed Payne rearrangement process.This methodology has been used as the key step in a five-step enantioselective total synthesis of (+)-exo

Studies toward polyether antibiotics: stereospecific synthesis of polysubstituted tetrhydropyrans

A stereospecific and general method for the preparartion of trans-tetrahydropyrans 1 and cis-tetrahydropyrans 2 from acyclic precursors are described.Compound 12, a possible intermediate for the synthesis of antibiotic X-14547A, has been synthesized.