865411-30-9Relevant academic research and scientific papers
The gem-dialkyl effect as a test for preliminary diphosphine chelate opening in a reductive elimination reaction
Arthur, Kathryn L.,Wang, Qi L.,Bregel, Dawn M.,Smythe, Nicole A.,O'Neill, Bridget A.,Goldberg, Karen I.,Moloy, Kenneth G.
, p. 4624 - 4628 (2005)
A significant kinetic effect of the placement of gem-dialkyl substituents in the carbon backbone of a bidentate phosphine ligand on a reductive elimination reaction involving chelate opening as a preliminary step has been documented. This observation conf
