865446-74-8

Upstream product

• 865446-73-7 (2R,3S)-4-{(R)-6-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-2-[3-(4-methoxy-benzyloxy)-propyl]-6-[(E)-2-((S)-toluene-4-sulfinyl)-vinyl]-5,6-dihydro-4H-pyran-3-yl}-2,3-dimethyl-butan-1-ol 
• 98-59-9 p-toluenesulfonyl chloride 
• 259540-48-2 (2R,3R)-1,4-bis[(4S)-4-(methylethyl)-2-oxo(1,3-oxazolidin-3-yl)]-2,3-dimethylbutane-1,4-dione 
• 851370-20-2 2,2-Dimethyl-propionic acid (2R,3S)-4-{(R)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-[3-(4-methoxy-benzyloxy)-propyl]-6-[(E)-2-((S)-toluene-4-sulfinyl)-vinyl]-5,6-dihydro-4H-pyran-3-yl}-2,3-dimethyl-butyl ester 
• 851370-25-7 2,2-Dimethyl-propionic acid (2R,3S)-4-{(R)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-[3-(4-methoxy-benzyloxy)-propyl]-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-3-yl}-2,3-dimethyl-butyl ester 
• 851370-24-6 2,2-Dimethyl-propionic acid (2R,3S)-4-[(R)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-trifluoromethanesulfonyloxy-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-3-yl]-2,3-dimethyl-butyl ester 
• 851370-26-8 2,2-Dimethyl-propionic acid (2R,3S)-4-{(R)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-hydroxymethyl-2-[3-(4-methoxy-benzyloxy)-propyl]-5,6-dihydro-4H-pyran-3-yl}-2,3-dimethyl-butyl ester 
• 851370-36-0 2,2-Dimethyl-propionic acid (2R,3S)-4-{(S)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-6-formyl-2-[3-(4-methoxy-benzyloxy)-propyl]-5,6-dihydro-4H-pyran-3-yl}-2,3-dimethyl-butyl ester 
• 851370-35-9 2,2-Dimethyl-propionic acid (2R,3S)-4-[(R)-6-((S)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-hydroxy-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-3-yl]-2,3-dimethyl-butyl ester 
• 851370-23-5 (R)-6-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-6-triisopropylsilanyloxymethyl-tetrahydro-pyran-2-one 
• 851370-21-3 2,2-Dimethyl-propionic acid (2R,3R)-4-iodo-2,3-dimethyl-butyl ester 
• 851370-34-8 2,2-Dimethyl-propionic acid (2R,3R)-4-hydroxy-2,3-dimethyl-butyl ester 
• 5866-39-7 L(+)-tartaric acid 
• 127253-15-0 (2R,3R)-2,3-dimethyl-butane-1,4-diol 

Relevant academic research and scientific papers

An approach to the imine ring system of pinnatoxins

(Chemical Equation Presented) A concise stereoselective approach to the spirobicyclic imine fragment of pinnatoxins and pteriatoxins is described. The approach relies on a tandem reaction sequence involving consecutive sigmatropic rearrangements to build