86554-23-6Relevant academic research and scientific papers
Nickel-Catalyzed Selective Cross-Coupling of Chlorosilanes with Organoaluminum Reagents
Naganawa, Yuki,Guo, Haiqing,Sakamoto, Kei,Nakajima, Yumiko
, p. 3756 - 3759 (2019/09/12)
Nickel-catalyzed cross-coupling reactions of chlorosilanes with organoaluminum reagents were developed. An electron-rich Ni(0)/PCy3 complex was found to be an effective catalyst for the desired transformation. The reaction of dichlorosilanes 1 proceeded to give the corresponding monosubstituted products 2. Trichlorosilanes 4 underwent selective double substitution to furnish the corresponding monochlorosilanes 2. Overall, the selective synthesis of a series of alkylmonochlorosilanes 2 from di- and trichlorosilanes was achieved using the present catalytic systems.
OXIDATIVE CLEAVAGE OF SILICON-CARBON BONDS IN ORGANOSILICON FLUORIDES TO ALCOHOLS
Tamao, K.,Kakui, T.,Akita, M.,Iwahara, T.,Kanatani, R.,et al.
, p. 983 - 990 (2007/10/02)
Certain functional silyl groups have been shown to be synthetically equivalent to the OH group.All of the C-Si bonds in organosilicon fluorides, K2 and RnSiF4-n (n=1,2,3) are cleaved by m-chloroperbenzoic acid (MCPBA) in DMF to give the corresponding alcohols in high yields.Although the reaction with RSiF5(2-) and RSiF3 proceeds without any additive, cleavage of R2SiF2 and R3SiF requires, respectively, a catalytic or excess amount of KF.A triorganoethoxysilane also undergoes similar oxidative cleavage reactions in the presence of an excess amount of KF.The MCPBA-oxidation of exo- and endo-2-norbornyl-silicate and -trifluorosilane proceeds stereospecifically with retention of configuration at carbon.A remarkable solvent effect has been observed in the oxidative cleavage of RSiF3.A plausible mechanism involves a hexacoordinate silicon species in which the organic group intramolecularly migrates from Si to O of the coordinated MCPBA.
