86594-31-2Relevant academic research and scientific papers
Acid-catalyzed Backbone Rearrangement of 5,6-Epoxyalnusanes and Preparation of Daturadiol
Tori, Motoo,Takai, Masaki,Matsumoto, Yuzo,Moriyama, Yoshihiko,Tsuyuki, Takahiko,et al.
, p. 2490 - 2495 (1984)
Epoxidation of alnus-5-en-3β-yl acetate with m-chloroperbenzoic acid gave a 5β,6β-epoxide as a main product together with a 5α,6α-epoxide as a minor product.Treatment of the α-epoxide with BF3*OEt2 afforded a 1(10),5-diene and a mixt
EPOXIDATION OF ALNUS-5-EN-3β-YL ACETATE AND CONVERSION OF DENDROPANOXIDE INTO DATURADIOL
Tori, Motoo,Takai, Masaki,Matsumoto, Yuzo,Moriyama, Yoshihiko,Tsuyuki, Takahiko,et al.
, p. 527 - 530 (2007/10/02)
Contrary to the reported literature, the main epoxide derived from alnus-5-en-3β-yl acetate (1) was shown to be a β-epoxide.Daturadiol (=olean-12-ene-3β,6β-diol) was prepared from dendropanoxide via 1 and its α-epoxide.
