Acid-catalyzed Backbone Rearrangement of 5,6-Epoxyalnusanes and Preparation of Daturadiol

DOI: 10.1246/bcsj.57.2490

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2490 - 2495 (1984)

Update date:2022-08-05

Topics: Preparation Acid-Catalyzed

Authors:

Tori, Motoo

Takai, Masaki

Matsumoto, Yuzo

Moriyama, Yoshihiko

Tsuyuki, Takahiko

et al. et al.

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Article abstract of DOI:10.1246/bcsj.57.2490

Epoxidation of alnus-5-en-3β-yl acetate with m-chloroperbenzoic acid gave a 5β,6β-epoxide as a main product together with a 5α,6α-epoxide as a minor product.Treatment of the α-epoxide with BF₃*OEt₂ afforded a 1(10),5-diene and a mixt

Full text of DOI:10.1246/bcsj.57.2490

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