Acid-catalyzed Backbone Rearrangement of 5,6-Epoxyalnusanes and Preparation of Daturadiol

DOI: 10.1246/bcsj.57.2490

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2490 - 2495 (1984)

Update date:2022-08-05

Topics: Preparation Acid-Catalyzed

Authors:

Tori, Motoo

Takai, Masaki

Matsumoto, Yuzo

Moriyama, Yoshihiko

Tsuyuki, Takahiko

et al. et al.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1246/bcsj.57.2490

Epoxidation of alnus-5-en-3β-yl acetate with m-chloroperbenzoic acid gave a 5β,6β-epoxide as a main product together with a 5α,6α-epoxide as a minor product.Treatment of the α-epoxide with BF₃*OEt₂ afforded a 1(10),5-diene and a mixt

Full text of DOI:10.1246/bcsj.57.2490

Products guided by the article

Product name:C₃₇H₅₄O₃

Cas No:86594-31-2

R&D Labs maybe for 86594-31-2

AstaTech ( Chengdu) BioPharmaceutical Corp.

website:http://www.astabiochem.cn/

Contact:+86-15198215156-15198215156

Address:SICHUAN CHENGDU
Shanghai Topchem Co., LTD

website:http://www.shtopchem.com/

Contact:0086-0576-87776998

Address:room no 1608,xuhui business building yude road,xujiahui street, xuhui district
Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Angelisun(Chongqing) Pharmaceutical Co., LTD.

Contact:+86-23-68030926-816

Address:D1-7 Tech & Entrepreneurs Park, Kecheng Road, Erlang Hi-Tech Areas, Chongqing, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD

Contact:29-63685658 63685359

Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China

Relevant to this article

The 'one-pot' syntheses of α,α′-diphosphino-substituted imines: A unique reaction of bulky bis(dialkylamino)chlorophosphines

Doi:10.1039/b009867l
(2001)
Observations on the activation of mitomycin C. Requirements for C-10 functionalization

Doi:10.1021/ja00167a097
(1990)
A Simple and Efficient Synthesis of Chiral Acetic Acid of High Optical Purity

Doi:10.1021/jo00168a027
(1983)
Synthesis of 5-(Substituted Phenyl) 4-Acetyl-2-methylthio-Δ²-1,3,4-thiadiazolines and their Oxidation with Potassium Permanganate

Doi:10.1039/P19830000967
(1983)
Saponin and Sapogenol. XXXV. Chemical constituents of Astragali Radix, the root of Astragalus membranaceus Bunge. (2). Astragalosides I, II, and IV, acetylastragaloside I and isoastragalosides I and II

Doi:10.1248/cpb.31.698
(1983)
Doi:10.1021/ja01123a031
(1952)

Article Doi