866036-95-5

Basic information

• Product Name: tert-butyl 1-methyl-3-butenyl[(4-methylphenyl)sulfonyl]carbamate
• Synonyms: tert-butyl 1-methyl-3-butenyl[(4-methylphenyl)sulfonyl]carbamate
• CAS NO: 866036-95-5
• Molecular Weight: 339.456
• Mol File: 866036-95-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyl 1-methyl-3-butenyl[(4-methylphenyl)sulfonyl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl 1-methyl-3-butenyl[(4-methylphenyl)sulfonyl]carbamate(866036-95-5)
• EPA Substance Registry System: tert-butyl 1-methyl-3-butenyl[(4-methylphenyl)sulfonyl]carbamate(866036-95-5)

Safety Data

• Hazardous Substances Data: 866036-95-5(Hazardous Substances Data)

Upstream product

• 2117-11-5 4-pentyn-2-ol 
• 111957-98-3 Pent-4-en-2-ol 
• 18303-04-3 N-[(tert-butoxy)carbonyl]-4-methylbenzenesulfonamide 

Downstream Products

• 2031-38-1 (+/-)-4-methyl-N-(pent-4-en-2-yl)benzenesulfonamide 

Relevant articles and documents

A detailed investigation of the aza-prins reaction

The development of a Lewis acid-promoted aza-Prins reaction to form piperidines and pyrrolidines is described. Indium trichloride has been found to be a highly successful and mild Lewis acid for promoting this reaction. A thorough mechanistic investigation is described, including the factors that influence the formation of the 5- or 6-membered ring product(s). The Royal Society of Chemistry.

A new, highly stereoselective approach to pyrrolidines via overall 5-endo-trig cyclisations of homoallylic tosylamides

Iodocyclisations of E-homoallylic tosylamides 7 lead to excellent yields of either 2,5-trans- or 2,5-cis-3-iodopyrrolidines (10 or 11), depending upon the reaction conditions.