866090-31-5Relevant articles and documents
Selective cross-metathesis of C-allyl-glycosides
Timmer, Mattie S. M.,Chumillas, Marta Vinciano,Donker-Koopman, Wilma E.,Aerts, Johannes M. F. G.,Van Der Marel, Gijsbert A.,Overkleeft, Herman S.,Van Boom, Jacques H.
, p. 335 - 351 (2005)
The efficient and selective cross-metathesis (CM) of both the α- and β-anomers of C-allyl-glucose and N-acetyl-C-allyl-glucosamine with electron-deficient olefins is reported. The applicability of our CM approach in the synthesis of glycoside-conjugates i