866097-03-2Relevant academic research and scientific papers
Direct arylation reactions catalyzed by Pd(OH)2/C: Evidence for a soluble palladium catalyst
Parisien, Mathieu,Valette, Damien,Fagnou, Keith
, p. 7578 - 7584 (2007/10/03)
Palladium hydroxide on carbon (Pearlman's catalyst) effectively catalyzes direct arylation reactions of aryl iodides and bromides, providing excellent arylation-to-hydrodehalogenation ratios (>30:1) with broad scope for both intra- and intermolecular arylation processes. Studies aimed at determining the nature of the active catalyst indicate that an active homogeneous palladium species is produced under the reaction conditions.
