866129-67-1Relevant academic research and scientific papers
Base-induced cyclization of 1-benzyloxy-2,2,4,4-tetramethylpentan-3-ones: Intramolecular nucleophilic addition of an anion of a benzyl ether to the carbonyl moiety without the Wittig rearrangement or protophilic decomposition
Matsumoto, Masakatsu,Watanabe, Nobuko,Ishikawa, Akio,Murakami, Hiroyuki
, p. 2395 - 2396 (1997)
Alkyl benzyl ethers bearing a carbonyl moiety in the alkyl chain (1) cyclize effectively, without the Wittig rearrangement or protophilic decomposition, to give hydroxytetrahydrofurans (trans-2) on treatment with ButOK in DMSO at room temperatu
Intramolecular charge-transfer-induced chemiluminescent decomposition of 1,2-dioxetanes bearing a phenylmethanide anion
Watanabe, Nobuko,Mizuno, Toshiyuki,Matsumoto, Masakatsu
, p. 9569 - 9585 (2007/10/03)
Dioxetanes (1) bearing a phenyl moiety substituted with a methylène or methine having an electron-withdrawing group(s) (-CH2-Ew or -CH(X)-Ew) and dioxetane (2) bearing a 3-(l-cyanoethenyl)phenyl group were synthesized. Treatment of dioxetanes (
