866415-98-7

Basic information

• Product Name: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester
• Synonyms: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester
• CAS NO: 866415-98-7
• Molecular Weight: 859.38
• Mol File: 866415-98-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester(866415-98-7)
• EPA Substance Registry System: (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester(866415-98-7)

Safety Data

• Hazardous Substances Data: 866415-98-7(Hazardous Substances Data)

Upstream product

• 866415-87-4 C₂₀H₂₂O₆ 
• 193354-06-2 (E)-hex-3-ene-1,6-diyl dibenzoate 
• 122167-22-0 7-octenylmagnesium bromide 
• 57042-08-7 Diethyl trans-hex-3-enedioate 
• 29311-53-3 (E)-3-hexene-1,6-dioic acid 
• 866415-93-2 (2S,3R,6S)-2-Decyl-6-{(S)-3-iodo-1-[(E)-2-((S)-toluene-4-sulfinyl)-vinyloxy]-propyl}-3-methoxymethoxy-tetrahydro-pyran 
• 866415-94-3 (2S,3R,6S)-2-Decyl-3-methoxymethoxy-6-[(2S,5R)-5-((S)-toluene-4-sulfinylmethyl)-tetrahydro-furan-2-yl]-tetrahydro-pyran 
• 866415-92-1 (2S,4S)-4-[(2S,5R,6S)-6-((E)-Dec-2-enyl)-5-methoxymethoxy-tetrahydro-pyran-2-yl]-2-phenyl-[1,3]dioxane 
• 866415-95-4 (2R,5S)-5-((2S,5R,6S)-6-Decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-carbaldehyde 
• 866415-97-6 4-(tert-butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid 
• 866415-89-6 (2S,4S)-4-[(S)-3-[1,3]Dithian-2-yl-1-(4-methoxy-benzyloxy)-propyl]-2-phenyl-[1,3]dioxane 
• 866415-91-0 [(2S,3R,6S)-3-Hydroxy-6-((2S,4S)-2-phenyl-[1,3]dioxan-4-yl)-tetrahydro-pyran-2-yl]-acetic acid ethyl ester 
• 862603-90-5 Toluene-4-sulfonic acid (R)-2-hydroxy-undec-10-enyl ester 

Downstream Products

• 866416-01-5 (E)-(4R,15R)-4-(tert-Butyl-dimethyl-silanyloxy)-15-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-15-hydroxy-2-phenylsulfanyl-pentadec-12-enoic acid 
• 866416-00-4 (E)-(5R,16R)-5-(tert-Butyl-dimethyl-silanyloxy)-16-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-3-phenylsulfanyl-oxacyclohexadec-13-en-2-one 

Relevant articles and documents

Stereoselective synthesis of (-)-jimenezin

Total synthesis of jimenezin was achieved via radical cyclization of β-alkoxyacrylate and β-alkoxyvinyl sulfoxide intermediates and intramolecular olefin metathesis reaction.