862603-90-5

Upstream product

• 2695-48-9 8-Bromo-1-octene 
• 113826-06-5 (R)-glycidyl tosylate 
• 1011298-78-4 (10R)-undec-1-ene-10,11-diol 
• 98-59-9 p-toluenesulfonyl chloride 
• 122167-22-0 7-octenylmagnesium bromide 

Downstream Products

• 866415-98-7 (R)-4-(tert-Butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid (R)-1-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-but-3-enyl ester 
• 866416-01-5 (E)-(4R,15R)-4-(tert-Butyl-dimethyl-silanyloxy)-15-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-15-hydroxy-2-phenylsulfanyl-pentadec-12-enoic acid 
• 866416-00-4 (E)-(5R,16R)-5-(tert-Butyl-dimethyl-silanyloxy)-16-[(2R,5S)-5-((2S,5R,6S)-6-decyl-5-methoxymethoxy-tetrahydro-pyran-2-yl)-tetrahydro-furan-2-yl]-3-phenylsulfanyl-oxacyclohexadec-13-en-2-one 
• 866415-97-6 4-(tert-butyl-dimethyl-silanyloxy)-2-phenylsulfanyl-tridec-12-enoic acid 
• 862603-95-0 (S)-3-((2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridecyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-31-4 (S)-3-((E)-(2R,13R)-2-(tert-Butyl-dimethyl-silanyloxy)-13-{(2S,5R,2'S,5'R)-5'-[(S)-1-(tert-butyl-dimethyl-silanyloxy)-undecyl]-octahydro-[2,2']bifuranyl-5-yl}-13-hydroxy-tridec-10-enyl)-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-29-0 (S)-3-[(R)-2-(tert-Butyl-dimethyl-silanyloxy)-undec-10-enyl]-5-methyl-3-phenylsulfanyl-dihydro-furan-2-one 
• 862603-92-7 toluene-4-sulfonic acid 2-(tert-butyl-dimethyl-silanyloxy)-undec-10-enyl ester 

Relevant academic research and scientific papers

Total synthesis of 27-hydroxy-bullatacin and its C-15 epimer, and studies on their inhibitory effect on bovine heart mitochondrial complex I functions

The total synthesis of 27-hydroxybullatacin and its C-15 epimer has been achieved using rhenium(VII) oxides-mediated and Co(modp)2-catalyzed oxidative cyclization (OC), diastereoselective alkynylation, Brown's enantioselective allylboration, an

Stereoselective syntheses of rolliniastatin 1, rollimembrin, and membranacin

A radical cyclization of β-alkoxyvinyl sulfoxides-Pummerer rearrangement-allylation protocol was successfully applied to the synthesis of the threol cis/threol cis/erythro bis-oxolane moiety in rolliniastatin 1 (1), rollimembrin (2), and membranacin (3).

Stereoselective synthesis of (-)-jimenezin

Total synthesis of jimenezin was achieved via radical cyclization of β-alkoxyacrylate and β-alkoxyvinyl sulfoxide intermediates and intramolecular olefin metathesis reaction.