866476-14-4Relevant academic research and scientific papers
Palladium(II)- and mercury(II)-catalyzed rearrangements of propargyl acetates
Caruana, Patrick A.,Frontier, Alison J.
, p. 10646 - 10656 (2008/02/12)
The scope and utility of the metal-catalyzed rearrangement of propargyl acetates first reported by Rautenstrauch were expanded. Treatment of a series of appropriate acetate substrates with Pd(II)- and Hg(II)-catalysts afforded synthetically useful fused 5
Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters
Bhanu Prasad,Yoshimoto, Francis K.,Sarpong, Richmond
, p. 12468 - 12469 (2007/10/03)
A highly selective and efficient Pt-catalyzed pentannulation reaction beginning from propargylic esters is described. The key to this reaction is the use of a PtCl2(PPh3)2/PhIO catalyst combination that allows the in situ
