866495-97-8Relevant academic research and scientific papers
Synthesis and characterisation of the platinum complexes [PtCl(CCl=PAr)(PPh3)2] and [PtCl(CCl=PAr′)(PPh 3)2] as potential intermediates in the preparation of phosphaalkynes
Cornet, Stéphanie M.,Dillon, Keith B.,Goeta, Andrés E.,Howard, Judith A.K.,Roden, Mark D.,Thompson, Amber L.
, p. 3630 - 3637 (2005)
Oxidative addition reactions of Cl2CPR (R = 2,4,6- tris(trifluoromethyl)phenyl (Ar) or 2,6-bis(trifluoromethyl)phenyl (Ar′) with Pt(PPh3)4 yield the cis and trans (at platinum) complexes [PtCl(ClCPAr)(PPh3)2] and [PtCl(ClCPAr′) (PPh3)2]. All starting materials and intermediates have been characterised by NMR spectroscopy. The crystal and molecular structures of the trans-platinum complexes have been determined by single-crystal X-ray diffraction at low temperature.
