86660-74-4

Basic information

• Product Name: Thiophene, 3-azido-4-(1-cyclohexen-1-yl)-
• CAS NO: 86660-74-4
• Molecular Formula: C10H11N3S
• Molecular Weight: 205.283
• Mol File: 86660-74-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Thiophene, 3-azido-4-(1-cyclohexen-1-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Thiophene, 3-azido-4-(1-cyclohexen-1-yl)-(86660-74-4)
• EPA Substance Registry System: Thiophene, 3-azido-4-(1-cyclohexen-1-yl)-(86660-74-4)

Safety Data

• Hazardous Substances Data: 86660-74-4(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 38071-56-6 3-bromo-2-cyclohex-1-enyl-thiophene 

Downstream Products

• 86660-76-6 ((C₄H₂S)(C₆H₈)N(C₆H₅)B)2O 

Relevant articles and documents

Thermal Decomposition of o-Azidobithienyls

Thermal decomposition of the six possible o-azidobithienyls (1)-(6) has been investigated as a possible source of the hitherto unknown dithienopyrrole ring system.It was found that the nature and yield of products and the temperature required for decomposition are strongly dependent on the structure of the starting azides. 3-Azido-2,2'-bithienyl (1) and 3-azido-2,3'-bithienyl (2) gave 4H-dithienopyrrole (7) and 4H-dithienopyrrole (8), respectively, in very good yields. 4-Azido-3,3'-dithienyl (3) and 4-azido-2',3-bithienyl (4) were relatively stable under the same conditions, but polymer ic materials were obtained when the thermal decomposition was performed under more vigorous conditions.By contrast, 2-azido-3,3'-bithienyl (5) and 2-azido-2',3-bithienyl (6) extrude nitrogen at room temperature resulting in ring-opening fragmentation.Thermolysis of 3-azido-2-cyclohex-1-enylthiophen (11) and 4-azido-3-cyclohex-1-enylthiophen (12) were also investigated to elucidate the different behavioural patterns exhibited by the 3-azidothienyl derivatives.