866612-65-9

Basic information

• Product Name: [(η5-indenyl)Ru(PPh3)(2-pyridylmethyl-2,4-dinitrophenyl ketazine)]PF6
• CAS NO: 866612-65-9
• Molecular Weight: 924.741
• Mol File: 866612-65-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [(η5-indenyl)Ru(PPh3)(2-pyridylmethyl-2,4-dinitrophenyl ketazine)]PF6(CAS DataBase Reference)
• NIST Chemistry Reference: [(η5-indenyl)Ru(PPh3)(2-pyridylmethyl-2,4-dinitrophenyl ketazine)]PF6(866612-65-9)
• EPA Substance Registry System: [(η5-indenyl)Ru(PPh3)(2-pyridylmethyl-2,4-dinitrophenyl ketazine)]PF6(866612-65-9)

Safety Data

• Hazardous Substances Data: 866612-65-9(Hazardous Substances Data)

Upstream product

• 75491-10-0 2-acetylpyridine 2,4-dinitrophenylhydrazone 
• 241152-08-9 [(η5-indenyl)(triphenylphosphine)(acetonitrile)ruthenium(II)] hexafluorophosphate 

Relevant articles and documents

New mononuclear ruthenium complexes of η5-cyclichydrocarbon containing azine ligands: Syntheses, spectral and structural studies

A series of mononuclear indenyl and pentamethylcyclopentadienyl ruthenium(II) complexes of formulation [(η5-L3) Ru(PPh3)(L2)]X, (where L3 = indenyl, pentamethylcyclopentadienyl; X = PF6 or BF4 and L 2 = azine ligands) have been prepared by the reaction of [(η5-L3)Ru(PPh3)2(CH 3CN)]X with the appropriate azine ligands in methanol or dichloromethane/benzene mixture. The reaction of nitro substituted azine ligands with the complexes [(η5-L3)Ru(PPh3) 2(CH3CN)]X are solvent dependent. All these complexes were isolated as their PF6 or BF4 salts. The complexes were fully characterized with the help of microanalyses, FT-IR and NMR spectroscopy. The molecular structure of representative complexes 5c and 6a were established by single X-ray crystallography.